Citation | 10.1016/j.combustflame.2022.112547 |
---|---|
Type | Mass-selected threshold photoelectron spectrum |
Further references | 10.1063/1.4984304 10.1016/j.nima.2009.08.069 |
T / K | 1500 |
Source | Pyrolysis |
Resolution / meV | 20 |
Flux normalization | yes |
Comments | Sample (2,4,4-trimethyl-2-pentene) dilluted in argon (0.05 %) expansion through a 100 um pinhole and subsequent pyrolysis (1500 K), mass resolution 200, field: 213 V/cm, i2PEPICO setup (CRF) |
Date & facility | 2017/2018 & SLS/VUV |
Date entered | 2022-09-19 |
Citation | 10.1016/j.combustflame.2022.112547 |
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Type | Photoionization spectrum |
Further references | 10.1063/1.4984304 10.1016/j.nima.2009.08.069 |
T / K | 1500 |
Source | Pyrolysis |
Resolution / meV | 20 |
Flux normalization | yes |
Comments | Sample (2,4,4-trimethyl-2-pentene) dilluted in argon (0.05 %) expansion through a 100 um pinhole and subsequent pyrolysis (1500 K), mass resolution 200, field: 213 V/cm, i2PEPICO setup (CRF) |
Date & facility | 2017/2018 & SLS/VUV |
Date entered | 2022-09-19 |
Type | Franck-Condon simulation |
---|---|
Further references | Program: Gaussian 16rev. A.03 suite |
T / K | 500 |
Level of theory | B3LYP/6-31G(d,p) |
Convolution FWHM / meV | 25 |
0-0 transition / eV | 9.79 |
Comments | FC simulation of methyl radical ground state |
Date & facility | 2021/03 & PSI Merlin 6 |
Date entered | 2022-09-19 |