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TPES 9.9-11.5 eV X 2Π(2A′, 2A″) ← X 3A″transition

Citation 10.1063/5.0010035
Type Mass-selected threshold photoelectron spectrum
Further references DOI of the beamline: 10.1107/S0909049512010588
DOI of the instrument: 10.1063/1.4937624
DOI of the experiment: 10.1063/1.4918634
T / K 215
Source microwave flow tube discharge reactor
Resolution / meV 17
Flux normalization yes
Comments Species created in a flow discharge reactor by a mix between acetonitrile and atomic fluor 1 ms of mixing time, temperature in the reactor: room temperature, pressure in reactor: 1 Torr, total flow in reactor: 1200 sccm, DC extraction field used: 35 V/cm, mass resolving power: 1900, energy scale with a precision of 5 meV, calibrated with methyl radical. Translational temperature of the radicals: 215 K The adiabatic ionization energy takes into account the Renner-Teller effect as referred in 10.1063/1.5011152
Date & facility 2020 SOLEIL Synchrotron DESIRS Beamline
Date entered 2024-07-23
TT, GGA, DM