About
Database
| Aliases | monomethylaluminum |
|---|---|
| Mass / amu | 42.02 |
| Sum formula | AlCH3 |
| InChI | InChI=1S/CH3.Al/h1H3 |
| CAS | 76392-49-9 |
| PubChem | 16685210 |
| Structure |  |
| AIE / eV | 7.89 |
| VIE / eV | 7.89 |
| AIE comment | 10.1021/acs.jpca.5c02601 |
| VIE comment | 10.1021/acs.jpca.5c02601 |
| Citation | 10.1021/acs.jpca.5c02601 |
|---|---|
| Type | Mass-selected threshold photoelectron spectrum |
| Further references | 10.1063/1.3082016 10.1016/j.nima.2009.08.069 |
| T / K | 650 |
| Source | Pyrolysis |
| Resolution / meV | 5 |
| Flux normalization | No |
| Comments | Trimethylalluminium was diluted in argon and expanded through a SiC reactor.Mass resolution 200, field: 213 V/cm, i2PEPICO (CRF) setup |
| Date & facility | SLS |
| Date entered | 2025-06-18 |
| Citation | 10.1021/acs.jpca.5c02601 |
|---|---|
| Type | Franck-Condon simulation |
| Further references | 10.1002/wcms.81 10.1002/wcms.1546 |
| T / K | 800 |
| Level of theory | CCSD(T)/cc-pVTZ |
| Convolution FWHM / meV | 40 |
| 0-0 transition / eV | 7.89 |
| Comments | Simulation was made with EzSpectrum. Calculations were performed with Orca 5.0.3 |
| Date & facility | 2025 Universität Würzburg |
| Date entered | 2025-06-18 |