PSI VUV About Database

ms-TPES 7.6-8.6 eV

Citation 10.1002/anie.201703433
Type Mass-selected threshold photoelectron spectrum
Further references 10.1063/1.3082016
10.1016/j.nima.2009.08.069
T / K 1050
Source Pyrolysis
Resolution / meV 5
Flux normalization no
Comments Aminomethylpyridine precursor at 0.3-0.5 bar (abs.) Ar buffer gas. Expanded through a 100 µm pinhole into a SiC pyrolysis reactor. electric field 120 V/cm, iPEPICO setup, mass resolution 100.
Date & facility 2016/2017, PSI, SLS
Date entered 2023-01-09
PH

FC-Simulation 7.6-8.6 eV

Citation 10.1002/anie.201703433
Type Franck-Condon simulation
Further references Gaussian09/16 eZSpectrum
T / K 500
Level of theory B3LYP/6-311G(2d,d,p)
Convolution FWHM / meV 25
0-0 transition / eV 7.70
Date & facility 2016/2017, PSI, SLS
Date entered 2023-01-09
PH