PSI VUV About Database

ms-SPES 8.4-10.3

Citation 10.1039/c8cp00510a
Type Mass-selected slow photoelectron spectrum
Further references DOI of the beamline: 10.1107/S0909049512010588
DOI of the instrument: 10.1063/1.4937624
DOI of the experiment: 10.1063/1.4918634
T / K Rotational: 150 K
Source microwave discharge flow tube reactor
Resolution / meV 17
Flux normalization yes
Comments Species created in a flow discharge reactor by a mix between propyne and atomic fluor Reactor temperature: 294 K, pressure in reactor: 1 Torr, extraction field: 88 V/cm, mass resolving power: 1900, energy scale with a precision of 3 meV, calibrated with Kr 5s. N.B.: this spectrum is composed of both the l-C3H and the c-C3H isomers. The first peak at 9.12 eV is assigned to the state X1Σ+. No FC simulation available in this article due to a Renner-Teller effect on the ground state of the neutral molecule.
Date & facility 2015 SOLEIL Synchrotron DESIRS Beamilne
Date entered 2024-07-02
TT, GGA

PIS 8.4-10.3

Citation 10.1039/c8cp00510a
Type Photoionization spectrum
Further references DOI of the beamline: 10.1107/S0909049512010588
DOI of the instrument: 10.1063/1.4937624
DOI of the experiment: 10.1063/1.4918634
T / K Translational: 150 K
Source microwave discharge flow tube reactor
Resolution / meV 17
Flux normalization yes
Comments Species created in a flow discharge reactor by a mix between propyne and atomic fluor Reactor temperature: 294 K, pressure in reactor: 1 Torr, extraction field: 88 V/cm, mass resolving power: 1900, energy scale with a precision of 3 meV, calibrated with Kr 5s. N.B.: this spectrum is composed of both the l-C3H and the c-C3H isomers. No FC simulation available in this article due to a Renner-Teller effect on the ground state of the neutral molecule.
Date & facility 2015 SOLEIL Synchrotron DESIRS Beamline
Date entered 2024-07-03
TT, GGA